iPod batteries that have a chemistry design of either lithium ion or lithium polymer will over time regardless of usage will experience power loss to the point of non-functioning. In fact contained within your ipod battery is a design and chemistry make-up that impacts your battery life far more than your usage activity and there is no amount of conditioning you can do to prevent the ultimate power loss of your ipod battery.
We know that batteries are rated by their voltage, their mAh, and of course the chemicals contained within. These three technical facts about your battery give some insight into the actual life of (energy stored within) your battery. But the length of time an ipod battery can operate is not linear to the amount of energy stored in the battery.
In fact their are four ongoing problems with your ipod battery that affects performance and the extended battery life of your ipod. They are: declining capacity, increasing internal resistance, elevated self-discharge, and premature voltage cut-off on discharge.
These are more complex issues that are beyond user control and are wholly contained within your ipod battery and within your ipod itself! As we will see these issues (declining capacity, increasing internal resistance, elevated self-discharge, and premature voltage cut-off on discharge) do more to cause iPod Battery Degradation and iPod Power Loss than your typical iPod owner could ever do.
Declining capacity is when the amount of charge a battery can hold gradually decreases due to usage, aging, and with some chemistry, lack of maintenance. iPod batteries are specified to deliver about 100 percent capacity when new but after usage and aging and lack of conditioning a iPod battery's capacity will drop. This is normal. If you are using an ipod battery (or any lithium-ion or lithium-polymer battery) when your battery's capacity reaches 60% to 70% the iPod battery will need to be replaced.
Standard industry practice will warranty a battery above 80%. Below 80% typically means you have used the practical life of a battery. Thus the threshold by which a battery can be returned under warranty is typically 80%.
Loss of Charge Acceptance
The loss of charge acceptance of the Li ion/polymer batteries is due to cell oxidation. Cell oxidation is when the cells of the battery lose their electrons. This is a normal process of the battery charge creation process. In fact every time you use your ipod battery a loss of charge acceptance occurs (the charge loss allows your battery to power your ipod). Capacity loss is permanent. Li ion/polymer batteries cannot be restored with cycling or any other external means. The capacity loss is permanent because the metals used in the cells run for a specific time only and are being consumed during their service life.
Internal resistance, known as impedance, determines the performance and runtime of a battery. It is a measure of opposition to a sinusoidal electric current. A high internal resistance curtails the flow of energy from the battery to a iPod device. The aging of the battery cells contributes, primarily, to the increase in resistance, not usage. Expect a typical life span of a Li ion/polymer battery to be one to three years, whether it is used or not. The internal resistance of the Li ion batteries cannot be improved with cycling (recharging). Cell oxidation, which causes high resistance, is non-reversible and is the ultimate cause of battery failure (energy may still be present in the battery, but it can no longer be delivered due to poor conductivity).
All batteries have an inherent self-discharge. The self-discharge on nickel-based batteries is 10 to 15 percent of its capacity in the first 24 hours after charge, followed by 10 to 15 percent every month thereafter. Li ion battery's self-discharges about five percent in the first 24 hours and one to two percent thereafter. At higher temperatures, the self-discharge on all battery chemistries increases. The self-discharge of a battery increases with age and usage. Once a battery exhibits high self-discharge, little can be done to reverse the effect.
Premature Voltage Cut-Off
Some iPods do not fully utilize the low-end voltage spectrum of an ipod battery. The ipod device itself cuts off before the designated end-of-discharge voltage is reached and battery power remains unused. For example, a ipod that is powered with a single-cell Li ion battery and is designed to cut-off at 3.7V may actually cut-off at 3.3V. Obviously the full potential of the battery and the device is lost (not utilized). Why? It could be something with elevated internal resistance and or iPod operations at warm ambient temperatures. iPods that load the battery with current bursts are more receptive to premature voltage cut-off than analog equipment. High cut-off voltage is mostly equipment related, not battery.
Until next time – Dan Hagopian, BatteryShip.com
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